Magnetically Grafted Carbon Nanotubes Synthesis and Its Oriented Nanochannels Construction in the Poly(Vinylidene Fluoride) (PVDF) Ultrafiltration Membranes
نویسندگان
چکیده
Carbon nanotubes (CNTs) with hollow nanochannels have attracted much attention in preparing high-performance water treatment membranes. In this paper, the grafting polymer chains, including alkynyl terminated poly(methyl methacrylate) methacrylate (PMMA) single chain and PMMA-b-poly (ethylene glycol) [P(PEGMA)] diblock molecular were synthesized by reversible addition-fragmentation transfer (RAFT) polymerization. A UV-induced click reaction was used to graft different linear polymers onto surface of magnetic thiol-functionalized carbon (mCNTs-SH). The poly(vinylidene fluoride) (PVDF) composite ultrafiltration membrane within oriented prepared using phase inversion field orientation. TEM XRD results confirmed that grafted a had good nano-dispersion orientation array effects PVDF membrane. contact angle mCNT-g-diblock chain-based 48.5°, significantly enhancing PEGMA segments. CTNs’ attained higher flux. As mCNTs membrane, flux reached 17.6 LMH (five times greater than pure membrane), while weight cut-off (MWCO) for PEG1400 rejection could reach 80%.
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ژورنال
عنوان ژورنال: Separations
سال: 2023
ISSN: ['2297-8739']
DOI: https://doi.org/10.3390/separations10040249